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Silica-Grafted Neodymium Catalysts for the Production of Ultra-High Molecular Weight 1,4-cis-Polyisoprene

ChemCatChem, 2018, 10, 1905

From special Issue on Supported Molecular Catalysts

E. Le Roux, Y. Liang, R. Anwander

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Modification of Silica-supported Tungsten Neosilyl Oxo Precatalysts: Impact of Substituted Phenol on Activity and Stability in Olefin Metathesis

Catal. Sci. Technol., 2016, 6, 8532

Y. Bouhoute, I. del Rosal, K. Szeto, N. Merle, D. Grekov, A. De Mallmann, E. Le Roux, L. Delevoye, R. Gauvin, L. Maron, M. Taoufik

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New Synthetic Approach Towards Well-defined Silica Supported Tungsten Bis-oxo, Active Catalysts for Olefin Metathesis

Catal. Commun., 2018, 108, 51

C. Larabi, N. Merle, F. Lequemener, P. Rouge, E. Berrier, R. M. Gauvin, E. Le Roux, A. de Mallmann, K. C. Szeto, M. Taoufik

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Immobilization of Heteroleptic Bis(oxazoline) Zinc Catalysts on SBA-15 for Asymmetric Hydrosilylation

Organometallics, 2015, 34, 5146

E. Le Roux, A. De Mallmann, N. Merles, M. Taoufik,  R. Anwander

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Preparation and Characterization of Metallacalixarenes Anchored to a Mesoporous Silica SBA-15 LP as Potential Catalysts

Microporous Mesoporous Mater., 2014, 188, 77

J. Espinas , J. Pelletier, K. C. Szeto , N. Merle, E. Le Roux, C. Lucas, A. De Mallmann, J.-M. Basset, M. Taoufik, J. Thivolle-Caza

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Heterogenization of Lanthanum and Neodymium Monophospha-cyclopentadienyl Bis(tetramethylaluminate) Complexes onto Periodic Mesoporous Silica SBA-15

Organometallics, 2012, 31, 6526

E. Le Roux, Y. Liang, K. W. Törnroos, F. Nief,  R. Anwander

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A Well-Defined Silica-Supported Aluminium Alkyl Through an Unprecedented, Consecutive Two-Step Protonolysis–Alkyl Transfer Mechanism

Chem. Commun., 2011, 47, 2979

J. Pelletier, J. Espinas, N. Vu, S. Norsic, A. Baudouin, L. Delevoye, J. Trébosc, E. Le Roux, C. Santini, J.-M. Basset, R. M. Gauvin, M. Taoufik

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Grafting of Peralkylated LnII-AlIII Heterobimetallic Complexes onto Periodic Mesoporous Silica KIT-6

Dalton Trans., 2010, 39, 8552

From themed issue Bridging the gap in catalysis via multidisciplinary approaches

E. Le Roux, O. Michel, H.-M. Sommerfeldt, Y. Liang, C. Maichle-Mössmer, K. W. Törnroos, R. Anwander

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Selective and Unexpected Transformation of 2-Methylpropane to 2,3-Dimethylbutane and 2-Methylpropene to 2,3-Dimethylbutene Catalyzed by an Alumina-Supported Tungsten Hydride

Chem. Commun., 2009, 2523

N. Merle, F. Stoffelbach, M. Taoufik, E. Le Roux, J. Thivolle-Cazat, J.-M. Basset

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Direct Transformation of Ethylene into Propylene Catalyzed by a Tungsten Hydride Supported on Alumina: An Example of Trifunctional Single-Site Catalysis

Angew. Chem. Int., Ed. Engl., 2007, 46, 7202

Selected as ”Very Important Paper” by the Editors of Angew. Chem.

M. Taoufik, E. Le Roux, J. Thivolle-Cazat, J.-M. Basset

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Molecular Understanding of Alumina Supported Single-Site Catalysts by a Combination of Experiment and Theory

J. Am. Chem. Soc., 2006, 128, 9157

J. Joubert, F. Delbecq, P. Sautet, E. Le Roux, M. Taoufik, C. Thieuleux, F. Blanc, C. Copéret, J. Thivolle-Cazat, J.-M. Basset

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[(≡SiO)TaCl2Me2]: A Well-Defined Silica-Supported Tantalum(V) Surface Complex Precursor for the Selective Cocatalyst-Free Trimerization of Ethylene

Angew. Chem. Int., Ed. Engl., 2012, 51, 11886

Y. Chen, E. Callens, E. Abou-Hamad, N. Merle, A. White, M. Taoufik, C. Copéret, E. Le Roux, J.-M. Basset

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Shifting from Ziegler-Natta to Philips Catalyst? A Simple and Safe Access to Reduced Titanium Systems for Ethylene Polymerization

Macromol. Rapid Commun., 2011, 32, 1921

N. Popoff, J. Espinas, E. Gouré, O. Boyron,  E. Le Roux, Gauvin R. M., J.-M. Basset, A. De Mallmann, M. Taoufik

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Intramolecular Hydroamination/Cyclization of Aminoalkenes Catalyzed by Ln[N(SiMe3)2]3 Grafted onto Periodic Mesoporous Silicas

J. Am. Chem. Soc., 2010, 132,16368

E. Le Roux, Y. Liang, M. P. Storz, R. Anwander

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Non-Oxidative Coupling of Methane Catalysed by Supported Tungsten Hydride onto Alumina and Silica–Alumina in Classical and H2 Permeable Membrane Fixed-Bed Reactors

Chem. Commun., 2010, 46, 3985

K. C. Szeto, S. Norsic, L. Hardou, A. Baudoin, J. Thivolle-Cazat, E. Le Roux, S. Chakka, C. Papaioannou, J.-M. Basset, M. Taoufik

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Development of a Well-Defined Silica-Supported Tungstenocarbyne Complex as Efficient Heterogeneous Catalyst for Alkyne Metathesis

 J. Organomet. Chem., 2008, 693, 1733

N. Merle, M. Taoufik, M. Nayer, E. Le Roux,  R. M. Gauvin,  F. Lefebvre, J. Thivolle-Cazat, J.-M. Basset

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Silica-Alumina-Supported, Tungsten-Based Heterogeneous Alkane Metathesis Catalyst: Is it Closer to a Silica- or an Alumina-Supported System?

Adv. Synth. Catal., 2007, 349, 231

From special Issue on Olefin Metathesis

E. Le Roux, M. Taoufik, A. Baudouin, C. Copéret, J. Thivolle-Cazat, J.-M. Basset, G. J. Sunley, B. M. Maunders

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Alumina Supported Tungsten Hydrides, New Efficient Catalysts for Alkane Metathesis

 Top. Catal., 2006, 40, 65

M. Taoufik, E. Le Roux, C. Copéret, J. Thivolle-Cazat, J.-M. Basset, B. M. Maunders, G. J. Sunley

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Tantalum Hydrides Supported on MCM-41 Mesoporous Silica: Activation of Methane and Thermal Evolution of the Tantalum-Methyl species

Organometallics, 2006, 25, 15697

S. Soigner, M. Taoufik, E. Le Roux, G. Saggio,  F. Lefebvre, A. de Mallmann, J. Thivolle-Cazat, J.-M. Basset, G. J. Sunley, B. M.  Maunders

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Well-Defined Surface Tungstenocarbyne Complexes through the Reaction of [W(≡CtBu)(CH2tBu)3] with Silica

Organometallics, 2005, 24, 4274

E. Le Roux, M. Taoufik, M. Chabanas, D. Alcor, A. Beaudoin, C. Copéret, J. Thivolle-Cazat, J.-M. Basset, A. Lesage, S. Hediger, L. Emsley

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Development of Tungsten-Based Heterogeneous Alkane Metathesis Catalysts Through a Structure-Activity Relationship

Angew. Chem., Int. Ed., 2005, 44, 6755

E. Le Roux, M. Taoufik, C. Copéret, A. de Mallmann, J. Thivolle-Cazat, J.-M. Basset, B. M. Maunders, G. J. Sunley

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Primary Products and Mechanistic Considerations in Alkane Metathesis

J. Am. Chem. Soc., 2005, 127, 8604

J.-M. Basset, C. Copéret, L. Lefort, B. M. Maunders, O. Maury, E. Le Roux, G. Saggio, S. Soignier, D. Soulivong, G. J. Sunley, M. Taoufik, J. Thivolle-Cazat

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Detailed Structural Investigation of the Grafting of [Ta(=CHtBu)(CH2tBu)3] and [Cp*Ta(CH3)4] on Silica Partially Dehydroxylated at 700°C and the Activity of the Grafted Complexes toward Alkane Metathesis

J. Am. Chem. Soc., 2004, 126, 13391

E. Le Roux, M. Chabanas, A. Baudouin, A. de Mallmann, C. Copéret, E. A. Quadrelli, J. Thivolle-Cazat, J.-M. Basset, W. Lukens, A. Lesage, L. Emsley, G. J. Sunley

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